<< It has long been known that crystalline materials should be good conductors when they have an odd number of electrons in each repeating cell of the structure, but may be poor conductors when the number is even. However, sometimes this formula does not work, with one case being "Mottness," a property based on the work of Sir Nevill Mott. According to that theory, when there is strong repulsion between electrons in the structure, it leads the electrons to become "localized"-paralyzed, in other words-and unable to move around freely to create an electric current. >>
<< For the current study, (..) the research group decided to look at tantalum disulfide, a material with 13 electrons in each repeating structure, which should therefore make it a conductor. However, it is not, and there has been controversy over whether this property is caused by its "Mottness" or by a pairing structure. >>
<< The exact nature of the insulating state and of the phase transitions in tantalum disulfide have been long-standing mysteries, and it was very exciting to find that Mottness is a key player, aside from the pairing of the layers. This is because theorists suspect that a Mott state could set the stage for an interesting phase of matter known as a quantum spin liquid. >> Christopher Butler.
Jens Wilkinson. 'Tantalizing' clues about why a mysterious material switches from conductor to insulator.
RIKEN. May 18, 2020.
AA << also observe the collapse of Mottness at an extrinsically re-stacked termination, demonstrating that the microscopic mechanism of insulator-metal transitions lies in degrees of freedom of inter-layer stacking. >>
C. J. Butler, M. Yoshida, et al. Mottness versus unit-cell doubling as the driver of the insulating state in 1T-TaS2. Nat Commun 11, 2477. doi: 10.1038/ s41467-020-16132-9. May 18, 2020
