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Visualizzazione post con etichetta chirality. Mostra tutti i post
Visualizzazione post con etichetta chirality. Mostra tutti i post

sabato 19 novembre 2022

# gst: apropos of swarms: local couplings, chirality, lattices of vortices, beating clusters, interacting phase waves among swarmalators.

AA << study the emergent behaviors of a population of swarming coupled oscillators, dubbed 'swarmalators'. (..)  Here (they) expand this work by adding more realistic features: local coupling, non-identical natural frequencies, and chirality. This more realistic model generates a variety of new behaviors including lattices of vortices, beating clusters, and interacting phase waves. Similar behaviors are found across natural and artificial micro-scale collective systems, including social slime mold, spermatozoa vortex arrays, and Quincke rollers. >>

Steven Ceron, Kevin O'Keeffe, Kirstin Petersen. Diverse Behaviors in Non-Uniform Chiral and Non-Chiral Swarmalators. arXiv: 2211.06439v1 [nlin.AO]. Nov 11, 2022.

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keyword 'swarm' in FonT

keyword 'chiral' in FonT

keyword 'vortex' in FonT

keyword 'vortice' in Notes
(quasi-stochastic poetry)

Keywords: gst, behav, behavior, behaviour, swarm, swarmalators, chirality, chiral swarmalators, non-chiral swarmalators, vortex, vortex array, vortices, vorticity, slime mold.





venerdì 13 maggio 2022

# evol: spontaneous, immediate asymmetry, the chiral twist


<< When holding a right hand in front of a mirror, one can see a reflected image of a left hand and vice versa. In 1848, Louis Pasteur discovered that organic molecules are much like our hands: they come in mirror-image pairs of left- and right-handed variants. Nowadays, we know that this handedness or chirality (from the Greek word for "hand") is a hallmark of organic molecules. >>

<< Organic molecules are rich in carbon atoms, which form bonds to create either a right or a left "nano-hand." Yet, puzzlingly, life almost always selects to exclusively use one of the two mirror-image twins—a phenomenon called homochirality. For example, terrestrial life is based on left-handed amino acids and right-handed sugars. >>️️

<< A model now proposes a novel explanation for the emergence of homochirality in life—a longstanding puzzle about the origin of life on Earth. >>️

<< Homochirality emerges spontaneously in prebiotic chemical networks that adapt to optimize energy harvesting from the environment. Previously, it was believed that chiral symmetry breaking requires multiple loops of auto-catalysis, which increasingly produces one enantiomer of a molecule while inhibiting the formation of the other. However, the IBS team's results showed that the underlying mechanism of symmetry breaking is very general, as it can occur in large reaction systems with many random molecules and does not require sophisticated network architectures. It was found that this sharp transition to homochirality stems from the self-configuration of the reaction network in order to achieve more efficient harvesting of energy from the environment. >>️

Learning chemical networks give life a chiral twist. Institute for Basic Science. Apr 26, 2022. 


William D. Pineros, Tsvi Tlusty. Spontaneous chiral symmetry breaking in a random driven chemical system. Nat Commun 13, 2244. doi: 10.1038/ s41467-022-29952-8. Apr 26, 2022.


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Keywords: evolution, gst, randomness, self-assembly, self-configuration, break symmetry, asymmetry, chiral, chirality  




lunedì 20 luglio 2020

# gst: apropos of 'strange states', the modulation of PdGa crystals from conventional to 'exotic' behaviors

<< In topological materials, electrons can display behavior that is fundamentally different from that in 'conventional' matter, and the magnitude of many such 'exotic' phenomena is directly proportional to an entity known as the Chern number. New experiments establish for the first time that the theoretically predicted maximum Chern number can be reached—and controlled—in a real material. >>

<<  in the topological semimetal palladium gallium (PdGa) one of the most common classifiers of topological phenomena, the Chern number, can reach the maximum value that is allowed in any metallic crystal. That this is possible in a real material has never been shown before. (..)  the team has established ways to control the sign of the Chern number, which might bring new opportunities for exploring, and exploiting, topological phenomena. >>

Cherned up to the maximum. Paul Scherrer Institute. Jul 9, 2020.


<< Here, (AA) show that the chiral crystal palladium gallium (PdGa) displays multifold band crossings, which are connected by exactly four surface Fermi arcs, thus proving that they carry the maximal Chern number magnitude of 4. By comparing two enantiomers, (They) observe a reversal of their Fermi-arc velocities, which demonstrates that the handedness of chiral crystals can be used to control the sign of their Chern numbers. >>

Niels B. M. Schroter, Samuel Stolz, et al. Observation and control of maximal Chern numbers in a chiral topological semimetal.  Science. Vol. 369, Issue 6500, pp. 179-183. doi: 10.1126/ science.aaz3480. Jul 10, 2020.


Also

D.J. Thouless, F. D.M. Haldane, J. M.Kosterlitz  << opened the door on an unknown world where matter can assume strange states. >> Oct 4, 2016




giovedì 23 gennaio 2020

# gst: self‐assembly of porous, chiral nano-patterns from simple building blocks.

<< Using a simple rod-like building block with hydroxamic acids at both ends scientists (..) created self- assembling porous, chiral nano structures.  >>

<< Like our left and right hands, the shape of two mirrored cage structures cannot be superimposed. Since the 19th century, academics have characterized this type of object symmetry as 'chiral,' from the ancient Greek meaning 'hand.' These kinds of molecules are frequently found in natural compounds. Chirality influences interactions of polarized light and magnetic properties and plays a vital role in life.  For example, our olfactory receptors react very differently to the two mirror images of the limonene molecule: one smells like lemon, the other like pine. This so-called chiral recognition is a process that can determine whether a molecule acts as medicine or poison. >>

Complex, porous, chiral nano-patterns arise from a simple linear building blocks. Technical University Munich. Jan 16, 2020.

https://m.phys.org/news/2020-01-complex-porous-chiral-nano-patterns-simple.html

<< Regrettably (in this specific experimental context), the end groups proved to be elusive >>

Chao Jing,  Bodong Zhang, et al. Snapshots of Dynamic Adaptation: Two‐Dimensional Molecular Architectonics with Linear Bis‐Hydroxamic Acid Modules. Angewandte Chemie International Edition. Volume 58, Issue 52. doi: 10.1002/anie.201912247. Oct 31, 2019. 

https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201912247

Also

keyword 'chiral' in FonT

https://flashontrack.blogspot.com/search?q=chiral

lunedì 13 gennaio 2020

# gst: a concrete image, chirality by dissipation, 'this effect actually owes its existence to dissipation'

<< Normally, dissipation alters or weakens existing quantum effects-but here we have an effect that actually owes its existence to dissipation, >>  Tilman Esslinger

<< "No scientist thinks in formulae," Albert Einstein allegedly once told his colleague Leopold Infeld. In fact, especially for physicists, who deal with such abstract things as quantum physics, it is often immensely useful to work with concrete images rather than mathematical symbols. >>

Oliver Morsch. Unexpected twist in a quantum system. ETH Zurich.  Jan 10, 2020.

https://m.phys.org/news/2020-01-unexpected-quantum.html

Nishant Dogra, Manuele Landini, et al.  Dissipation-induced structural instability and chiral dynamics in a quantum gas.  Science  20 Dec 2019:
Vol. 366, Issue 6472, pp. 1496-1499
DOI: 10.1126/science.aaw4465

https://science.sciencemag.org/content/366/6472/1496   

sabato 14 settembre 2019

# gst: nano entities that are both twisted and untwisted at the same time

<< Scientists who study the nanoscale-with molecules and materials 10,000 smaller than a pinhead-need to be able to test the way that some molecules twist, known as their chirality, because mirror image molecules with the same structure can have very different properties. >>

<< Recently, a new class of nanoscale materials have been developed to help distinguish the chirality of molecules. These so-called 'nanomaterials' usually consist of tiny twisted metal wires, that are chiral themselves. However, it has become very hard to distinguish the twist of the nanomaterials from the twist of the molecules they are supposed to help study. >>

To solve this problem AA << created a nanomaterial that is both twisted and it is not. This nanomaterial has equal number of opposite twists—meaning they cancel each other out.  >>

<< Using a mathematical analysis of the material's symmetry properties, the team discovered a few special cases, which can bring the 'hidden' twist to light and allow very sensitive detection of chirality in molecules. >>

Chris Melvin. Scientists create a nanomaterial that is both twisted and untwisted at the same time. University of Bath. Sep 13, 2019   https://m.phys.org/news/2019-09-scientists-nanomaterial-untwisted.html  

Christian Kuppe,  Xuezhi Zheng, et al. Measuring optical activity in the far-field from a racemic nanomaterial: diffraction spectroscopy from plasmonic nanogratings. Nanoscale Horizons.  Issue 5, 2019.  doi: 10.1039/C9NH00067D.   https://pubs.rsc.org/en/content/articlelanding/2019/NH/C9NH00067D