# ai-bot: Cybloids − Creation and Control of Cybernetic Colloids.

FIG. 11. Particle clusters formed for different parameters of the feedback potential.

AA << present an idea to create particles with freely selectable properties. The properties might depend, for example, on the presence of other particles (hence mimicking specific pair or many-body interactions), previous configurations (hence introducing some memory or feedback), or a directional bias (hence changing the dynamics). Without directly interfering with the sample, each particle is fully controlled and can receive external commands through a predefined algorithm that can take into account any input parameters. This is realized with computer-controlled colloids, which (AA) term cybloids - short for cybernetic colloids. >>

<< For a single particle, this programming can cause subdiffusive behavior or lend activity. For many colloids, the programmed interaction potential allows to select a crystal structure at wish. Beyond these examples, (AA) discuss further opportunities which cybloids offer. >>️

Debasish Saha, Sonja Tarama, et al. Cybloids − Creation and Control of Cybernetic Colloids. arXiv: 2408.00336v1 [cond-mat.soft]. 

https://arxiv.org/abs/2408.00336

Also: ai (artificial intell), bot, colloids, in https://www.inkgmr.net/kwrds.html 

Keywords: AI, Artificial Intell, BOT, AI-BOT, colloids, cybernetic colloids, cybloids

# gst: controlled creation of point defects in 3D colloidal crystals

<< Crystal defects crucially influence the properties of crystalline materials and have been extensively studied. Even for the simplest type of defect—the point defect—however, basic properties such as their diffusive behavior, and their interactions, remain elusive on the atomic scale. >>️

Here AA << demonstrate in situ control over the creation of isolated point defects in a three-dimensional (3D) colloidal crystal allowing insight on a single-particle level. >>

AA << experimental model system provides a unique opportunity to shed light on the interplay between point defects, on the mechanisms of their diffusion, on their interactions, and on collective dynamics. >>️

Max P. M. Schelling, Janne-Mieke Meijer. Controlled creation of point defects in three-dimensional colloidal crystals. Phys. Rev. E 109, L062601. Jun 4, 2024.

https://journals.aps.org/pre/abstract/10.1103/PhysRevE.109.L062601

Also: colloids, defect, error, transition,  in https://www.inkgmr.net/kwrds.html 

Keywords: gst, colloids, defect, error, transition

# gst: soft and stiff modes in colloidal particle networks

<< Floppy microscale spring networks are widely studied in theory and simulations, but no well-controlled experimental system currently exists. >> 

AA << show that square lattices consisting of colloid-supported lipid bilayers functionalized with DNA linkers act as microscale floppy spring networks. (AA) extract their normal modes by inverting the particle displacement correlation matrix, showing the emergence of a spectrum of soft modes with low effective stiffness in addition to stiff modes that derive from linker interactions. >>

<< Evaluation of the softest mode, a uniform shear mode, reveals that shear stiffness decreases with lattice size. >>

 AA << results reveal the importance of entropic steric effects. >>

️

Julio Melio, Silke E. Henkes, Daniela J. Kraft. Soft and Stiff Normal Modes in Floppy Colloidal Square Lattices. Phys. Rev. Lett. 132, 078202. Feb 14, 2024. 

https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.132.078202

Also: particle, nano, colloids, network, in https://www.inkgmr.net/kwrds.html

Keywords: gst, particle, nano, colloids, network, colloidal network

# gst: anisotropic active depletion around a self-propelled non-interactive colloids; three characteristic states could be identified.

<< Active colloids in a bath of inert particles of smaller size cause anisotropic depletion. >>️

Here AA << combine mesoscale hydrodynamic simulation as well as theoretical analysis to examine the physical origin for the active depletion around a self-propelled noninteractive colloid. >>️

Their << results elucidate that the variable hydrodynamic effect critically governs the microstructure of the depletion zone. Three characteristic states of anisotropic depletion are identified, depending on the strength and stress of activity. >>️

<< Furthermore, (AA) demonstrate that such depletion in nonequilibrium results in various clusters with ordered organization of squirmers, which follows a distinct principle contrary to that of the entropy scenario of depletion in equilibrium. >>

️

Lijun Dai, Haixiao Wan, et al. Hydrodynamic Anisotropy of Depletion in Nonequilibrium. Phys. Rev. Lett. 131, 134002. Sep 27, 2023. 

https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.131.134002

Also: particle, colloids, in https://www.inkgmr.net/kwrds.html

Keywords: gst, particles, colloids, depletion, squirmers, self-propulsion systems

# gst: stochastic resonance mediated by optimal noise level values; transport of colloidal particles induced by substrate concentration oscillations.

AA << show the existence of a  stochastic resonant regime in the transport of active colloidal particles under confinement. The periodic addition of substrate to the system causes the spectral amplification to exhibit a maximum for an optimal noise level value. The consequence of this is that particles can travel longer distances with lower fuel consumption. The stochastic resonance phenomenon found allows the identification of optimal scenarios for the transport of active particles, enabling them to reach regions that are otherwise difficult to access, and may therefore find applications in transport. >>️

J. D. Torrenegra-Rico, A. Arango-Restrepo, J. M. Rubi. Optimal transport of active particles induced by substrate concentration oscillations. Phys. Rev. E 108, 014134. July 28, 2023.

https://journals.aps.org/pre/abstract/10.1103/PhysRevE.108.014134

Img: https://twitter.com/PhysRevE/status/1687119409096089602

Also: particle, colloids, noise, in:  https://www.inkgmr.net/kwrds.html

Keywords: gst, particle, colloids, noise, stochastic resonance, substrate oscillation

# gst: like the slender body theory, the effect of curvature on the diffusion of colloidal bananas.

<< Anisotropic colloidal particles exhibit complex dynamics which play a crucial role in their functionality, transport, and phase behavior.  >>️

AA << investigate the two-dimensional diffusion of smoothly curved colloidal rods—also known as colloidal bananas—as a function of their opening angle α >>️

<< the experimental results are consistent with slender body theory, indicating that the dynamical behavior of the particles arises primarily from their local drag anisotropy. These results highlight the impact of curvature on the Brownian motion of elongated colloidal particles, which must be taken into account when seeking to understand the behavior of curved colloidal particles. >>️

Justin-Aurel Ulbrich, Carla Fernández-Rico, et al. Effect of curvature on the diffusion of colloidal bananas. Phys. Rev. E 107, L042602. April 21, 2023.

https://journals.aps.org/pre/abstract/10.1103/PhysRevE.107.L042602

Img: https://twitter.com/PhysRevE/status/1650782974722338816

Also: gst, particle, in https://www.inkgmr.net/kwrds.html

Keywords: gst, colloids, particles, behavior

# chem: spontaneous reconfiguration of deformable nanoparticles (in response to environmental cues)

<< Deformable nanoparticles (NPs) offer unprecedented opportunities as dynamic building blocks that can spontaneously reconfigure during assembly in response to environmental cues. >>

<< deformable spherical NPs of radius 50 nm whose surface is tailored with octahedrally distributed charged patches and double-cap charged patches adapt their shape differently in response to changes in surface charge coverage and ionic strength. >>

AA << find shape transitions to rounded octahedra, faceted octahedra, faceted bowls, oblate spheroids, spherocylinders, dented beans, and dimpled rounded bowls. >>

AA << demonstrate that similar shape transitions can be achieved in deformable NPs of different sizes. >>️

Fanbo Sun, Nicholas E. Brunk, Vikram Jadhao. Shape control of deformable charge-patterned nanoparticles. Phys. Rev. E 107, 014502. Jan 10, 2023.

https://journals.aps.org/pre/abstract/10.1103/PhysRevE.107.014502

Img https://twitter.com/PhysRevE/status/1613183219377086468

Also

keyword 'self-assembly' in FonT

https://flashontrack.blogspot.com/search?q=self-assembly

keyword 'nano' in FonT

https://flashontrack.blogspot.com/search?q=nano

keyword 'nano' in Notes 

(quasi-stochastic poetry)

https://inkpi.blogspot.com/search?q=nano

Keywords: chem, nano, nanoparticles,  NPs, self-assembly, colloids, polymers, vesicle structures.

# gst: ️apropos of spontaneous active matter, the active droploids.

<< Active matter comprises self-driven units, such as bacteria and synthetic microswimmers, that can spontaneously form complex patterns and assemble into functional microdevices. These processes are possible thanks to the out-of-equilibrium nature of active-matter systems, fueled by a one-way free-energy flow from the environment into the system. Here, (AA) take the next step in the evolution of active matter by realizing a two-way coupling between active particles and their environment, where active particles act back on the environment giving rise to the formation of superstructures. >>️

<< These structures hinge on mutually coupled structure formation processes of the colloids, which form an engine, and the surrounding solvent, which phase separates in regions of high colloidal density and encapsulates the engine within a droplet shell.  >>

️

Jens Grauer, Falko Schmidt, et al. Active droploids. arXiv:2109.10677v1 [cond-mat.soft]. Sep 22, 2021.

https://arxiv.org/abs/2109.10677

Also

keyword 'drop' | 'droplet' in FonT

https://flashontrack.blogspot.com/search?q=drop

https://flashontrack.blogspot.com/search?q=droplet

keyword 'goccia' in Notes (quasi-stochastic poetry): 

https://inkpi.blogspot.com/search?q=goccia

keywords: gst, drops, droplets, colloids, active matter, active droploids, self-assembly, solitons.

# gst: observing the crystallization process in a droplet

<< Crystallization is the assembly of atoms or molecules into highly ordered solid crystals, which occurs in natural, biological, and artificial systems. However, crystallization in confined spaces, such as the formation of the protein shell of a virus, is poorly understood. Researchers are trying to control the structure of the final crystal formed in a confined space to obtain crystals with desired properties, which requires thorough knowledge of the crystallization process. >>

AA << used a droplet of a colloid—a dispersion of liquid particles in another liquid, like milk—as a model for single atoms or molecules in a sphere. Unlike single atoms or molecules, which are too small to easily observe, the colloid particles were large enough to visualize using a microscope. This allowed the researchers to track the ordering of single particles in real time during crystallization. >>

<< We visualized the organization process of colloid particles in numerous droplets under different conditions to provide a picture of the crystallization process in a sphere, >> Peng Tan

<< Based on their observations, the team proposed that the crystallization process involved three stages: initial ordering on the surface "skin" of the droplet, nucleation and growth in the core of the droplet, and then slow ripening of the whole structure. First, a skin consisting of a single layer of ordered colloid particles rapidly formed on the droplet surface. Next, crystallization occurred in the core of the droplet, far from the crystallized skin. The competition between crystallization in these two regions controlled the structure of the final crystal. The researchers found that the "soft" (long-range) interactions between the negatively charged colloid particles affected their organization and the resulting crystal structure. These soft interactions are dominated by kinetics, that is, the interactions that form the fastest, rather than those that use the least energy to give the thermodynamically stable structure, illustrating that kinetics plays an important role in crystallization in a confined space. It was already known that thermodynamics contributes strongly to the final structure of crystals. >>

Having a ball: Crystallization in a sphere. University of Tokyo. Sep 21, 2020.

https://phys.org/news/2020-09-ball-crystallization-sphere.html

Chen Y., Yao Z., et al. Morphology selection kinetics of crystallization in a sphere. Nat. Phys. doi: 10.1038/ s41567-020-0991-9. Sep 21, 2020.

https://www.nature.com/articles/s41567-020-0991-9

Also

Control of material crystallization by agitation. Osaka University. Jun 08, 2017.

https://phys.org/news/2017-06-material-crystallization-agitation.html

keyword 'drop' or 'droplet' in FonT

https://flashontrack.blogspot.com/search?q=drop

https://flashontrack.blogspot.com/search?q=droplet

# gst: assembling colloidal spheres into rods of several lengths to walk above a pattern.

<< Detailed control over the motion of colloidal particles is relevant in many applications in colloidal science such as lab-on-a-chip devices. Here, (AA) use an external magnetic field to assemble paramagnetic colloidal spheres into colloidal rods of several lengths. The rods reside above a square magnetic pattern and are transported via modulation of the direction of the external magnetic field. >>

<< The rods behave like bipeds walking above the pattern. Depending on their length, the bipeds perform topologically distinct classes of protected walks. >>

<< Using such loops, (they) induce the collision of reactant bipeds, their polymerization addition reaction to larger bipeds, the separation of product bipeds from the educts, the sorting of different product bipeds, and also the parallel writing of a word consisting of several letters. >>

Mahla Mirzaee-Kakhki, Adrian Ernst, et al. Simultaneous polydirectional transport of colloidal bipeds. Nat Commun 11, 4670. doi: 10.1038/ s41467-020-18467-9. Sep 16, 2020.

https://www.nature.com/articles/s41467-020-18467-9

Controlled dynamics of colloidal rods. 

Bayreuth University. Sep 16, 2020. 

https://phys.org/news/2020-09-dynamics-colloidal-rods.html