# gst: when a soliton juggles ('catches' and 'throws') droplets

<< Jugglers normally work with solid objects, but a research team has now demonstrated a system that juggles liquid drops. (AA)  have previously shown that liquid drops can bounce in place above the surface of the same liquid—or bounce while moving across the surface—if the container is continuously vibrated (..) In these past experiments, the surface was nearly flat, except for waves generated by the bouncing drop. In the new work by undergraduate student Camila Sandivari of the University of Chile and her colleagues, the vibrations cause the liquid surface to form a large standing wave that actively “catches” and “throws” the drop during each cycle of its oscillation. The trapping of the drop is similar in principle to other types of wave traps, such as laser-based optical tweezers, and the system could potentially lead to new types of traps for larger objects. >>

AA << placed water mixed with a dye and a surface-tension-reducing agent in a 20-cm-long, 2.6-cm-wide basin that supports an unusual type of surface wave when the basin is vibrated in a specific frequency range. In this wave, rather than a series of oscillating peaks and valleys, there is only a single standing wave peak, called a soliton. However, this peak doesn’t oscillate uniformly across the basin’s short dimension (the width). A peak appears at one of the long walls coincident with a valley at the opposite wall, and then the peak and the valley switch places moments later, keeping a relatively flat “node” line along the central long axis of the basin. >>

AA << used a pipette to place a few-millimeter-wide drop of the same fluid just above the oscillating soliton, close to one of the long walls, and found that drops could be juggled for up to 90 minutes. The team attributes this unusual stability in part to a property of the soliton: if the drop wanders off-center, the oscillating surface wave pulls it back toward its center, similar to the way the laser field in optical tweezers is able to stably hold a small particle at its center. >>

David Ehrenstein. Juggling Water Drops. Physics 16, 21. Feb 10, 2023. 

https://physics.aps.org/articles/v16/21

Also

keyword 'drop' | 'droplet' | 'droploids' in FonT

https://flashontrack.blogspot.com/search?q=drop

https://flashontrack.blogspot.com/search?q=droplet

https://flashontrack.blogspot.com/search?q=droploids

keyword 'goccia' in Notes 

(quasi-stochastic poetry)

https://inkpi.blogspot.com/search?q=goccia

keyword 'solitons' in FonT

https://flashontrack.blogspot.com/search?q=soliton

https://flashontrack.blogspot.com/search?q=solitons

Keywords: gst, solitons, drop, droplet, droploids, goccia

# gst: apropos of evaporation, puncturing of active drops

<< By virtue of self-propulsion, active particles impart intricate stresses to the background fluids. (..) this active stress can be utilized to greatly control evaporation dynamics of active drops. >>

AA << discover a new phenomenon of puncturing of the active drops, where the air-liquid interface of the drop undergoes spontaneous tearing and there occurs a formation of a new three-phase contact line due to the liquid-air interface hitting the liquid-solid interface through evaporation-driven mass loss. Post puncturing, (AA) see an inside-out evaporation of the drop, where the new contact line sweeps towards the pinned outer contact line of the drops, contrasting regular drops that straightaway shrink to zero volume with self-similar shape. >>

<< Furthermore, (..) the activity inside the drops can manipulate the three-phase contact-line dynamics, which for contractile drops can result in an up to 50% enhanced lifetime of the drop and 33% quicker evaporation for extensile drops. By analyzing the flux distribution inside the drop, (AA) gain insights on nonintuitive deposition patterns (e.g., ring galaxy type deposits that demonstrate controllable spatial gradients in the concentrations of the deposited particles) of active particles, which are oftentimes biological substances or bimetallic nanoparticles of interest. >>

Ghansham Rajendrasingh Chandel, Vishal Sankar Sivasankar, Siddhartha Das. Evaporation of active drops: Puncturing drops and particle deposits of ring galaxy patterns. Phys. Rev. Fluids 9, 033603. Mar 27, 2024. 

https://journals.aps.org/prfluids/abstract/10.1103/PhysRevFluids.9.033603

Also: drop, particle, evaporation, transition, in https://www.inkgmr.net/kwrds.html 

Keywords: gst, drop, particle, evaporation, transition, drop interactions, droplet, droploid

# gst: nonmonotonic appearance- disappearance behaviors of two unequal-sized miscible liquid drops

<< the coalescence process of two miscible liquid drops exhibits a nonmonotonic behavior of partial coalescence from appearance to disappearance and then reappearance with decreasing surface tension ratio. The strong lifting force of the intense Marangoni flow causes the reappearance of partial coalescence at higher surface tension difference between two drops. When the Ohnesorge number increases, high viscous forces restrict the propagation of Marangoni flow and do not favor the pinch-off, even in the presence of a significant surface tension difference. The generation of secondary drops at a considerable surface tension difference is also prevented for small parent drop size ratio. >>️

Swati Singh, Arun K. Saha. Effect of surface tension gradients on coalescence dynamics of two unequal-sized drops. Phys. Rev. Fluids 8, 053604. May 24, 2023. 

https://journals.aps.org/prfluids/abstract/10.1103/PhysRevFluids.8.053604

Also:  'drop' in https://www.inkgmr.net/kwrds.html  

Keywords: gst, behavior, drop, drop breakup, drop coalescence, drop interactions, droplet, droploid

# gst: predict the wetting of the wedge; why do the teapots always drip?

<<  The "teapot effect" has been threatening spotless white tablecloths for ages: if a liquid is poured out of a teapot too slowly, then the flow of liquid sometimes does not detach itself from the teapot, finding its way into the cup, but dribbles down at the outside of the teapot. >>

<< This phenomenon has been studied scientifically for decades—now a research team at TU Wien has succeeded in describing the "teapot effect" completely and in detail with an elaborate theoretical analysis and numerous experiments: An interplay of different forces keeps a tiny amount of liquid directly at the edge, and this is sufficient to redirect the flow of liquid under certain conditions. >>

<< Although this is a very common and seemingly simple effect, it is remarkably difficult to explain it exactly within the framework of fluid mechanics,  (..) We have now succeeded for the first time in providing a complete theoretical explanation of why this drop forms and why the underside of the edge always remains wetted, >>  Bernhard Scheichl.

<< The sharp edge on the underside of the teapot beak plays the most important role: a drop forms, the area directly below the edge always remains wet. The size of this drop depends on the speed at which the liquid flows out of the teapot. If the speed is lower than a critical threshold, this drop can direct the entire flow around the edge and dribbles down on the outside wall of the teapot. >>

<< The mathematics behind it is complicated—it is an interplay of inertia, viscous and capillary forces. The inertial force ensures that the fluid tends to maintain its original direction, while the capillary forces slow the fluid down right at the beak. The interaction of these forces is the basis of the teapot effect. However, the capillary forces ensure that the effect only starts at a very specific contact angle between the wall and the liquid surface. The smaller this angle is or the more hydrophilic (i.e. wettable) the material of the teapot is, the more the detachment of the liquid from the teapot is slowed down. >>

<< Interestingly, the strength of gravity in relation to the other forces that occur does not play a decisive role. Gravity merely determines the direction in which the jet is directed, but its strength is not decisive for the teapot effect. The teapot effect would therefore also be observed when drinking tea on a moon base, but not on a space station with no gravity at all. >>️

Why teapots always drip. Vienna University of Technology. Nov 08, 2021

https://phys.org/news/2021-11-teapots.html

Scheichl, B., Bowles, R., & Pasias, G. (2021). Developed liquid film passing a smoothed and wedge-shaped trailing edge: Small-scale analysis and the ‘teapot effect’ at large Reynolds numbers. Journal of Fluid Mechanics, 926, A25. doi: 10.1017/jfm.2021.612. Sep 8, 2021. 

http://dx.doi.org/10.1017/jfm.2021.612

keywords: gst, teapot effect, interfacial flows, thin films, boundary layers, Reynolds number, viscosity, viscous–inviscid interaction 

# gst: when volatile droplets dance across a surface erratically (along random trajectories)

<< When a drop of a volatile liquid is deposited on a uniformly heated wettable, thermally conducting substrate, one expects to see it spread into a thin film and evaporate. >>️

<< Contrary to this intuition, due to thermal Marangoni contraction, the deposited drop contracts into a spherical-cap-shaped puddle, with a finite apparent contact angle. Strikingly, this contracted droplet, above a threshold temperature, well below the boiling point of the liquid, starts to spontaneously move on the substrate in an apparently erratic way. >>️

Pallav Kant, Mathieu Souzy, et al. Autothermotaxis of volatile drops. Phys. Rev. Fluids 9, L012001. Jan 31, 2024. 

https://journals.aps.org/prfluids/abstract/10.1103/PhysRevFluids.9.L012001

Rachel Berkowitz. Hot Surfaces Make Droplets Move Erratically. Physics 17, s14. Jan 31, 2024. 

https://physics.aps.org/articles/v17/s14 

Also: drop, bubble, erratic

in https://www.inkgmr.net/kwrds.html

Keywords: gst, drop, bubble, erratic, thermotaxis, autothermotaxis

# gst: multi-component droplets may exhibit self-lubricating effects

<< Over the past decade, there has been a growing interest in the study of multicomponent drops. These drops exhibit unique phenomena, as the interplay between hydrodynamics and the evolving physicochemical properties of the mixture gives rise to distinct and often unregulated behaviors. >>

<< Of particular interest is the complex dynamic behavior of the drop contact line, which can display self-lubrication effect. The presence of a slipping contact line in self-lubricating multicomponent drops can suppress the coffee-stain effect, conferring valuable technological applications. >>

Huanshu Tan, Detlef Lohse, Xuehua Zhang. Self-Lubricating Drops. arXiv: 2403.01207v1 [physics.flu-dyn]. Mar 2, 2024

https://arxiv.org/abs/2403.01207

Also: drop droplet droploid, in https://www.inkgmr.net/kwrds.html

Keywords: drop, droplet, droploid, multicomponent drops, drop contact line, self-lubrication

# gst: apropos of weird transitions: from non-equilibrium conditions square droplets and liquid lattices can emerge.

<< Spontaneous emergence of organized states in materials driven by non-equilibrium conditions is of notable fundamental and technological interest. In many cases, the states are complex, and their emergence is challenging to predict. Here, (AA) show that an unexpectedly diverse collection of dissipative organized states emerges in a simple system of two liquids under planar confinement when driven by electrohydrodynamic shearing.

At low shearing, a symmetry breaking at the liquid-liquid interface leads to a one-dimensional corrugation pattern. 

At slightly stronger shearing, topological changes give raise to the emergence of Quincke rolling filaments, filament networks, and two-dimensional bicontinuous fluidic lattices. 

At strong shearing, the system transitions into dissipating polygonal, toroidal, and active droplets that form dilute gas-like states at low densities and complex active emulsions at higher densities. >>

Geet Raju, Nikos Kyriakopoulos, Jaakko V. I. Timonen. Diversity of non-equilibrium patterns and emergence of activity in confined electrohydrodynamically driven liquids. Science  Advances. Vol 7, Issue 38. doi: 10.1126/ sciadv.abh1642. 15 Sep 15, 2021.

https://www.science.org/doi/10.1126/sciadv.abh1642

<< Things in equilibrium tend to be quite boring, (..) It's fascinating to drive systems out of equilibrium and see if the non-equilibrium structures can be controlled or be useful. Biological life itself is a good example of truly complex behavior in a bunch of molecules that are out of thermodynamic equilibrium. >>  Jaakko Timonen.

Physicists make square droplets and liquid lattices. Aalto University. Sep 15, 2021. 

https://phys.org/news/2021-09-physicists-square-droplets-liquid-lattices.html

Also

keyword 'drop' | 'droplet' in FonT

https://flashontrack.blogspot.com/search?q=drop

https://flashontrack.blogspot.com/search?q=droplet

keyword 'goccia' in Notes (quasi-stochastic poetry): 

https://inkpi.blogspot.com/search?q=goccia

keywords: gst, drop, droplet, lattice, transition, out of equilibrium.

# gst: apropos of unexpected thresholds, the minimum temperature for levitating a droplet

<< During the Leidenfrost effect, a thin insulating vapor layer separates an evaporating liquid from a hot solid. (AA) demonstrate that Leidenfrost vapor layers can be sustained at much lower temperatures than those required for formation. >>

<< the explosive failure point is nearly independent of material and fluid properties, suggesting a purely hydrodynamic mechanism determines this threshold. >>️

Dana Harvey, Joshua Mendez Harper, Justin C. Burton. Minimum Leidenfrost Temperature on Smooth Surfaces. Phys. Rev. Lett. 127, 104501. Sep 1, 2021.

https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.127.104501

Christopher Crockett. The Minimum Temperature for Levitating Droplets. Physics 14, s107. Sep 1, 2021.

https://physics.aps.org/articles/v14/s107

Also

keyword 'drop' | 'droplet' in FonT

https://flashontrack.blogspot.com/search?q=drop

https://flashontrack.blogspot.com/search?q=droplet

keywords: gst, drop, droplet, waves, buckling, lubrication, convection, interfacial flows, threshold, levitation, bubble.

# gst: apropos of apparent erratic dynamics, the self-organization of drops bouncing on a vertically-vibrated surface

<< A drop bouncing on a vertically-vibrated surface may self-propel forward by Faraday waves and travels along a fluid interface. >>

<< A fine anal­ysis of the pairwise density function shows that while being dynamic, time-evolving and presenting many in­dications of a good mixing in the phase space, the sys­tem adopts in average preferred distances which origin has been rationalized by analysing the internal symme­try of the waves. Thus (AA) have shed light numerically on a statistical many-body wave self-organisation in an apparent erratic dynamics. >>

Adrien Hélias, Matthieu Labousse. Statistical self-organization of walking drops. arXiv:2201.07689v1 [cond-mat.soft]. Jan 19, 2022.

https://arxiv.org/abs/2201.07689

Also

keyword 'drop' | 'droplet' in FonT

https://flashontrack.blogspot.com/search?q=drop

https://flashontrack.blogspot.com/search?q=droplet

keyword 'goccia' in Notes (quasi-stochastic poetry): 

https://inkpi.blogspot.com/search?q=goccia

keywords: gst, drops, self-organization, erratic dynamics, erraticity

# gst: apropos of transitions, the transition from sticking to slipping.

<< From hydrogels and plastics to liquid crystals, soft solids cover a wide array of synthetic and biological materials that play key enabling roles in advanced technologies >>️

<< Attempts to study the interactions between soft solids and liquids have largely focused on the wetting of soft solids and its resulting deformation at equilibrium or in a quasi-static state. Here, (AA) consider the frequently encountered case of unsteady wetting of a liquid on a soft solid and show that transient deformation of the solid is necessary to understand unsteady wetting behaviours. >>️

AA << find that the initial spreading of the liquid occurs uninterrupted in the absence of solid deformation. This is followed by intermittent spreading, in which transient deformation of the solid at the three-phase contact line (CL) causes the CL motion to alternate alternation between CL sticking and slipping. (They) identify the spreading rate of liquids and the viscoelastic reacting rate of soft solids as the two competing factors in dictating intermittent spreading. (They)  formulate and validate experimentally the conditions required for the contact line to transition from sticking to slipping. By considering the growing deformation of soft solids as dynamic surface heterogeneities, (AA) proposed conditions for stick-slip transition in unsteady wetting on soft solids broaden the classical theory on wetting hysteresis on rigid solids. >>️

Surjyasish Mitra, Quoc Vo, Marcus Lin, Tuan Tran. Unsteady wetting of soft solids. arXiv:2211.07043v1 [cond-mat.soft]. Nov 13, 2022.

https://arxiv.org/abs/2211.07043

Also

keyword 'drop' | 'droplet' | 'droploids' in FonT

https://flashontrack.blogspot.com/search?q=drop

https://flashontrack.blogspot.com/search?q=droplet

https://flashontrack.blogspot.com/search?q=droploids

keyword 'goccia' in Notes 

(quasi-stochastic poetry) 

https://inkpi.blogspot.com/search?q=goccia

Keywords: gst, behav, behaviour, transition, soft solids, drop, droplet, sticking, slipping.

# life: apropos of transitions, a leap from chemistry to biology, the hypothesis of self-assembling droplets, the 'droplet world'.

AA << identify conditions suitable for concurrent peptide generation and self-assembly, and (..) show how a proliferating peptide-based droplet could be created by using synthesised amino acid thioesters as prebiotic monomers. Oligopeptides generated from the monomers spontaneously formed droplets through liquid–liquid phase separation in water. The droplets underwent a steady growth–division cycle by periodic addition of monomers through autocatalytic self-reproduction. Heterogeneous enrichment of RNA and lipids within droplets enabled RNA to protect the droplet from dissolution by lipids. >>

Matsuo, M., Kurihara, K. Proliferating coacervate droplets as the missing link between chemistry and biology in the origins of life. Nat Commun 12, 5487. doi: 10.1038/ s41467-021-25530-6. Sep 24,  2021.

https://www.nature.com/articles/s41467-021-25530-6

<< By constructing peptide droplets that proliferate with feeding on novel amino acid derivatives, we have experimentally elucidated the long-standing mystery of how prebiotic ancestors were able to proliferate and survive by selectively concentrating prebiotic chemicals, (..) Rather than an RNA world, we found that 'droplet world' may be a more accurate description, as our results suggest that droplets became evolvable molecular aggregates—one of which became our common ancestor. >> Muneyuki Matsuo.

Answering a century-old question on the origins of life. Hiroshima University. Sep 27, 2021. 

https://phys.org/news/2021-09-century-old-life.html

Also

keyword 'drop' | 'droplet' in FonT

https://flashontrack.blogspot.com/search?q=drop

https://flashontrack.blogspot.com/search?q=droplet

keyword 'transition' in FonT

https://flashontrack.blogspot.com/search?q=transition

keyword 'transizione' in Notes (quasi-stochastic poetry): 

https://inkpi.blogspot.com/search?q=transizione

keywords: life, originsoflife, transitions, drop, droplet

# gst: levitation in a temperature gradient: the two liquids don't mix

<< A drop or two of cold cream in hot coffee can go a long way toward improving one's morning. But what if the two liquids didn't mix? >>

AA << have now explained why under certain conditions a droplet of liquid should not coalesce with the liquid surface below. If the droplet is very cold, and the bath sufficiently hot, then the droplet should "levitate" on the bath's surface, as a result of the flows induced by the temperature difference >>

<< If you study that process mathematically, you can show the way in which temperature is changing in the droplet over time is exactly with this power law of 2/3 that we observed in our experiments >> Michela Geri.

Jennifer Chu. Study explains how droplets can 'levitate' on liquid surfaces. Nov 15, 2017

https://m.phys.org/news/2017-11-droplets-levitate-liquid-surfaces.html

Michela Geri, Bavand Keshavarz, et al. Thermal delay of drop coalescence.
Journal of Fluid Mechanics. 2017; 833  doi: 10.1017/jfm.2017.686  Nov 8, 2017.

https://www.cambridge.org/core/journals/journal-of-fluid-mechanics/article/thermal-delay-of-drop-coalescence/CB55985D6ADC2251BA5EA94C8021C18F#

# gst: apropos of modulational instabilities, the case of vortex-ring quantum droplets in a radially-periodic potential.

FIG. 11: (Color online) Typical examples of stable nested patterns with soliton and vortex QDs (quantum droplets)  which were created in adjacent radial troughs. In panels (a1-b4) the pattern was created from the initial dynamical states with parameters (N,S,On) = (46,0,2) and (N,S,On) = (35,1,1) in the outer and inner troughs, respectively. In panels (c1-d4) the input was taken with parameter sets (N,S,On) = (120,1,3) and (N,S,On) = (46,0,2) in the outer and inner troughs.

AA << establish stability and characteristics of two-dimensional (2D) vortex ring-shaped quantum droplets (QDs) formed by binary Bose-Einstein condensates. >>️

<< another noteworthy option is to construct a two-ring complex in which one vortex-ring component is subject to the MI  (modulational instability), hence it is replaced by an azimuthal soliton (or maybe several solitons), (..), while the vortex component trapped in another potential trough avoids the azimuthal MI and remains essentially axisymmetric. >>️

<< Examples of such heterogeneous robust states, produced by simulations of Eq. (3), are displayed in Fig. 11. Panels 11(a1-b4) show a complex in which the MI takes place in the outer circular trough, producing an azimuthal soliton which performs rotary motion, while the inner vortex ring is  modulationally stable. An opposite example is produced in Figs. 11(c1-d4), where the outer vortex ring remains stable against azimuthal perturbations, while the MI creates a soliton exhibiting the rotary motion in the embedded (inner) circular trough. The rotation direction of the soliton is driven by the vorticity sign of the underlying QD (quantum droplet). It is relevant to mention that the multi-ring potential considered here holds different vortex-ring or azimuthal-soliton states nearly isolating them from each other. (..) An additional problem, which is left for subsequent analysis, is interplay between adjacent radial modes in the case when the separation between the adjacent rings is essentially smaller. >>️

Bin Liu, Yi xi Chen, et al. Vortex-ring quantum droplets in a radially-periodic potential. arXiv: 2212.05838v1 [nlin.PS]. Dec 12, 2022.

https://arxiv.org/abs/2212.05838

Also

keyword 'drop' | 'droplet' | 'droploids' in FonT

https://flashontrack.blogspot.com/search?q=drop

https://flashontrack.blogspot.com/search?q=droplet

https://flashontrack.blogspot.com/search?q=droploids

keyword 'goccia' in Notes 

(quasi-stochastic poetry): 

https://inkpi.blogspot.com/search?q=goccia

keyword 'instability' | 'instabilities' in FonT

https://flashontrack.blogspot.com/search?q=instability

https://flashontrack.blogspot.com/search?q=instabilities

keyword 'instabile' in Notes 

(quasi-stochastic poetry)

https://inkpi.blogspot.com/search?q=instabile

Keywords: gst, drop, droplet, vortex, vortices, vortexes, vorticity, instability,  modulational instabilities

# gst: hidden complexity during the twinkle of a shrinking droplet

<< Captivating patterns found in the light scattered by an evaporating water droplet could be used to infer the properties of the droplet as it shrinks. >>

AA << collected the light that bounced off a spherical water droplet as the droplet shrunk, which happened naturally as it evaporated. The team observed twinkling patterns called Fano combs, which resemble the outlines of hedgehogs. >>

Ryan Wilkinson. Twinkling of a Shrinking Droplet Reveals Hidden Complexity. Physics 16, s9. Jan 24, 2023.

https://physics.aps.org/articles/v16/s9

AA << then fully explain it by expanding the quantum analogy. This turns the droplet into an “optical atom" with angular momentum, tunneling, and excited states. >>

Javier Tello Marmolejo, Adriana Canales, et al. Fano Combs in the Directional Mie Scattering of a Water Droplet. Phys. Rev. Lett. 130, 043804. Jan 24, 2023.

https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.130.043804

Also

keyword 'evaporation' in FonT

https://flashontrack.blogspot.com/search?q=evaporation

keyword 'drop' | 'droplet' | 'droploids' in FonT

https://flashontrack.blogspot.com/search?q=drop

https://flashontrack.blogspot.com/search?q=droplet

https://flashontrack.blogspot.com/search?q=droploids

keyword 'goccia' in Notes 

(quasi-stochastic poetry): 

https://inkpi.blogspot.com/search?q=goccia

Keywords: gst, drop, droplet, shrink, shrinking droplet, evaporation, transition

# gst: nematic order condensation and topological defects in inertial active nematics

<< Living materials at different length scales manifest active nematic features such as orientational order, nematic topological defects, and active nematic turbulence. Using numerical simulations (AA) investigate the impact of fluid inertia on the collective pattern formation in active nematics. >>️

<< an incremental increase in inertial effects due to reduced viscosity results in gradual melting of nematic order with an increase in topological defect density before a discontinuous transition to a vortex-condensate state. The emergent vortex-condensate state at low enough viscosities coincides with nematic order condensation within the giant vortices and the drop in the density of topological defects. (AA) further show flow field around topological defects is substantially affected by inertial effects. (..) no evidence of universal scaling at higher viscosities. >>

️

Roozbeh Saghatchi, Mehmet Yildiz, Amin Doostmohammadi. Nematic order condensation and topological defects in inertial active nematics. Phys. Rev. E 106, 014705. July 25, 2022.

https://journals.aps.org/pre/abstract/10.1103/PhysRevE.106.014705

Also: 'turbulence', 'vortex', 'defect', 'drop' in https://www.inkgmr.net/kwrds.html

Keywords: gst, behavior, collective behavior, patterns, turbulence, nematic turbulence, viscosity, vortex, defect, drop

# gst: active drops: from steady to chaotic self-propulsion

<< Individual chemically active drops suspended in a surfactant solution were observed to self-propel spontaneously with straight, helical, or chaotic trajectories. (..) strong advection (e.g., large droplet size) may destabilize a steadily self-propelling drop; once destabilized, the droplet spontaneously stops and a symmetric extensile flow emerges. If advection is strengthened even further in comparison with molecular diffusion, the droplet may perform chaotic oscillations. >>

Matvey Morozov, Sebastien Michelin. Nonlinear dynamics of a chemically-active drop: From steady to chaotic self-propulsion. J. Chem. Phys. 150, 044110 (2019). doi: 10.1063/1.5080539. Jan 31, 2019.  https://aip.scitation.org/doi/10.1063/1.5080539

# gst: apropos of transitions, evaporating binary microdroplets with phase segregation

<< Phase segregation triggered by selective evaporation can emerge in multicomponent systems, leading to complex physiochemical hydrodynamics. Recently, Li et al. (2018) and Kim & Stone (2018) reported a segregative behavior (i.e., demixing) in an evaporating binary droplet. In this work, by means of experiments and theoretical analysis, (AA) investigate the flow dynamics after the occurrence of the phase segregation. >>

<< First, (AA) experimentally reveal the overall physiochemical hydrodynamics of the evaporation process, including the segregative behavior and the resulting flow structure close to the substrate. By quantifying the evolution of the radial flow, (they) identify three successive life stages of the evaporation process. >>

<< At Stage I, a radially outward flow is observed. It is driven by the Marangoni effect. At the transition to Stage II, the radial flow partially reverses, starting from the contact line. This flow breaks the axial symmetry and remarkably is driven by the segregation itself. Finally at Stage III, the flow decays as the evaporation gradually ceases. At this stage the segregation has grown to the entire droplet, and the flow is again controlled by the Marangoni effect. The resulting Marangoni flow homogenizes the distribution of the entrapped volatile water over the whole droplet. >>️

Yaxing Li, Pengyu Lv, et al. Physiochemical hydrodynamics of the phase segregation in an evaporating binary microdroplet.arXiv:2208.07861v1 [physics.flu-dyn]  Aug 16, 2022.

https://arxiv.org/abs/2208.07861

Marangoni effect. 

https://en.m.wikipedia.org/wiki/Marangoni_effect   

https://youtu.be/vGb6t5Gfq6s   

Also

keyword 'drop' | 'droplet' in FonT

https://flashontrack.blogspot.com/search?q=drop

https://flashontrack.blogspot.com/search?q=droplet

Keywords: gst, droplet, transition, evaporation, phase transition, phase segregation, Marangoni flow

# gst: observing the crystallization process in a droplet

<< Crystallization is the assembly of atoms or molecules into highly ordered solid crystals, which occurs in natural, biological, and artificial systems. However, crystallization in confined spaces, such as the formation of the protein shell of a virus, is poorly understood. Researchers are trying to control the structure of the final crystal formed in a confined space to obtain crystals with desired properties, which requires thorough knowledge of the crystallization process. >>

AA << used a droplet of a colloid—a dispersion of liquid particles in another liquid, like milk—as a model for single atoms or molecules in a sphere. Unlike single atoms or molecules, which are too small to easily observe, the colloid particles were large enough to visualize using a microscope. This allowed the researchers to track the ordering of single particles in real time during crystallization. >>

<< We visualized the organization process of colloid particles in numerous droplets under different conditions to provide a picture of the crystallization process in a sphere, >> Peng Tan

<< Based on their observations, the team proposed that the crystallization process involved three stages: initial ordering on the surface "skin" of the droplet, nucleation and growth in the core of the droplet, and then slow ripening of the whole structure. First, a skin consisting of a single layer of ordered colloid particles rapidly formed on the droplet surface. Next, crystallization occurred in the core of the droplet, far from the crystallized skin. The competition between crystallization in these two regions controlled the structure of the final crystal. The researchers found that the "soft" (long-range) interactions between the negatively charged colloid particles affected their organization and the resulting crystal structure. These soft interactions are dominated by kinetics, that is, the interactions that form the fastest, rather than those that use the least energy to give the thermodynamically stable structure, illustrating that kinetics plays an important role in crystallization in a confined space. It was already known that thermodynamics contributes strongly to the final structure of crystals. >>

Having a ball: Crystallization in a sphere. University of Tokyo. Sep 21, 2020.

https://phys.org/news/2020-09-ball-crystallization-sphere.html

Chen Y., Yao Z., et al. Morphology selection kinetics of crystallization in a sphere. Nat. Phys. doi: 10.1038/ s41567-020-0991-9. Sep 21, 2020.

https://www.nature.com/articles/s41567-020-0991-9

Also

Control of material crystallization by agitation. Osaka University. Jun 08, 2017.

https://phys.org/news/2017-06-material-crystallization-agitation.html

keyword 'drop' or 'droplet' in FonT

https://flashontrack.blogspot.com/search?q=drop

https://flashontrack.blogspot.com/search?q=droplet

# gst: apropos of 1or2achoos (e.g. from Wuhan), the dynamics of turbulence in a fluid puff

<< Turbulence is everywhere -- in the movement of the wind, the ocean waves and even magnetic fields in space. It can also be seen in more transient phenomena, like smoke billowing from a chimney, or a cough. (..) Understanding this latter type of turbulence -- called puff turbulence -- is important not only for the advancement of fundamental science, but also for practical health and environmental measures, >>️

<< The very nature of turbulence is chaotic, so it's hard to predict, (..) Puff turbulence, which occurs when the ejection of a gas or liquid into the environment is disrupted, rather than continuous, has more complicated characteristics, so it's even more challenging to study. But it's of vital importance -- especially right now for understanding airborne transmission of viruses like SARS-CoV-2. >>️ Marco Edoardo Rosti. 

<< The new model, (..) includes how minute fluctuations within the puff behave, and how both large-scale and small-scale dynamics are impacted by changes in temperature and humidity. (..) at cooler temperatures (15°C or lower), (AA) model deviated from the classical model for turbulence. >>️

<< In the classical model, turbulence reigns supreme -- determining how all the little swirls and eddies within the flow behave. But once temperatures dipped, buoyancy started to have a greater impact. >>

<< The effect of buoyancy was initially very unexpected. It's a completely new addition to the theory of turbulent puffs,>> Marco Edoardo Rosti. ️

Secrets of COVID-19 transmission revealed in turbulent puffs. Okinawa Institute of Science and Technology (OIST). Aug 26, 2021. 

https://www.sciencedaily.com/releases/2021/08/210826111729.htm

Andrea Mazzino, Marco Edoardo Rosti. Unraveling the Secrets of Turbulence in a Fluid Puff. Phys. Rev. Lett. 127, 094501. Aug 25, 2021. 

https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.127.094501

Also

keyword 'drop' | 'droplet' in FonT:

https://flashontrack.blogspot.com/search?q=drop

https://flashontrack.blogspot.com/search?q=droplet

keyword 'turbulence' in FonT:

https://flashontrack.blogspot.com/search?q=turbulence

keyword 'turbolento' | 'turbolenza' in Notes (quasi-stochastic poetry): 

https://inkpi.blogspot.com/search?q=turbolento

https://inkpi.blogspot.com/search?q=turbolenza

keyword 'virus' | 'sars-cov-2' | 'sars' in FonT: 

https://flashontrack.blogspot.com/search?q=virus

https://flashontrack.blogspot.com/search?q=sars-cov-2

https://flashontrack.blogspot.com/search?q=sars

keyword 'virus' in Notes (quasi-stochastic poetry):

https://inkpi.blogspot.com/search?q=virus

# gst: apropos of transitions, droplet trajectories during single and collective bursting bubbles

<< Mechanisms of droplet production from bursting bubbles have been extensively studied for single bubbles, but remain sparsely investigated in more complex collective settings. >>️

<< In the collective bubbling experiment, subsurface quasimonodisperse bubbles are rising up to the surface where, depending on the surfactant concentration, they can either merge or assemble in rafts of monodisperse bubbles. Drop trajectories are recorded, analyzed, and shown to exhibit uniquely distinctive features for the different production mechanisms: centrifuge film drops are ejected sideways, and jet drops are ejected vertically. Different single-burst scalings are finally compared to the experimental size-velocity relationships, and reveal that drops coming from collective bubble bursting appear slower and more scattered than when coming from single bursting bubbles. >>️

B. Neel and L. Deike. Velocity and size quantification of drops in single and collective bursting bubbles experiments. Phys. Rev. Fluids 7, 103603. Oct 5, 2022. 

https://journals.aps.org/prfluids/abstract/10.1103/PhysRevFluids.7.103603

Also: 'when a superbubble can generate trains of shock waves'. Mar 6, 2019.

https://flashontrack.blogspot.com/2019/03/gst-astro-when-superbubble-can-generate.html

Also: 'transition', 'droplet', 'droploid', 'bubble', in: https://www.inkgmr.net/kwrds.html

Keywords: gst, transition, drop, droplet, droploid, bubble, collective dynamics,  fluid dynamics

PS: << they can either merge or assemble in rafts of monodisperse bubbles >> ; this is poetry, without unnecessary adjectives, anzicheforse ... FonT. Wed June 14, 2023 16:58 (cest)