# zoo: apropos of extreme dwarf entities, three new species of nano-hawk moths (Cautethia Grote, Sphingidae)

<< Hawk moths are known for being some of the largest night fliers in the insect world (..) three new species from The Bahamas are breaking records at the opposite end of the size spectrum. At about the length of a vitamin pill, they are among the smallest discovered. >>️

<< Hawk moths are a diverse group of insects, with some 1,700 species worldwide. In addition to their remarkable wingspans, they also have incredibly long proboscises, the straw-like tongues they use to siphon nectar.  The title for the world's longest proboscis is held by a hawk moth endemic to Madagascar, which comes in at just under 12 inches when fully unfurled. >>️

Brian V. Smith. New hawk moth species are among the smallest ever discovered. Florida Museum of Natural History. Jul 11, 2022. 

https://phys.org/news/2022-07-hawk-moth-species-smallest.html

Jacqueline Y. Miller, Deborah L. Matthews, Riley J. Gott. Three new species of Cautethia Grote (Lepidoptera: Sphingidae) from the Lucayan Archipelago and keys to West Indies species. Insecta Mundi. 0937,  1-28. Jun 24, 2022 (pdf).

https://centerforsystematicentomology.org/insectamundi/0937_Miller_etal_2022.pdf

Also

Apropos of extreme dwarf entities, the nano-chameleon (Brookesia nana). FonT.  Feb 9, 2021.

https://flashontrack.blogspot.com/2021/02/zoo-apropos-of-extreme-dwarf-entities.html

keyword 'nano' in FonT

https://flashontrack.blogspot.com/search?q=nano

keyword 'nano' in Notes 

(quasi-stochastic poetry)

https://inkpi.blogspot.com/search?q=nano

keywords: life, zoo, evol, dwarf, nano

# gst: apropos of transitions, reversing order-disorder of Janus nano particles confined in two dimensions

<< Janus particles with different patch sizes, confined to two dimensions, generate a series of patterns of interest to the field of nanoscience >>

AA << observe reverse melting, where for some densities the system melts under cooling. For a broad range of hydrophobic patch sizes (..), a reentrant transition from solid to liquid and then to an ordered phase emerges as temperature (T) decreases due to the formation of rhombus chains at low T.  This reentrant phase has pseudo long-range orientational order but short-range translational order, >>

The << work provides guidelines to study the melting and assembly of Janus particles in two dimensions, as well as mechanisms to generate phases with specific symmetry. >>️️

️

Yihao Liang, Boran Ma, Monica Olvera de la Cruz. Reverse order-disorder transition of Janus particles confined in two dimensions. Phys. Rev. E 103, 062607. Jun 9, 2021.

https://journals.aps.org/pre/abstract/10.1103/PhysRevE.103.062607

Also

keyword 'nano' in FonT

https://flashontrack.blogspot.com/search?q=nano

keyword 'nano' in Notes 

(quasi-stochastic poetry)

https://inkpi.blogspot.com/search?q=nano

# zoo; apropos of extreme dwarf entities, the nano-chameleon (Brookesia nana)

<< An international team, (..) has discovered a minuscule new species of chameleon.  (..) They have named the new species Brookesia nana. >>

 << At a body length of just 13.5 mm and a total length of just 22 mm including the tail, the male nano-chameleon is the smallest known male of all 'higher vertebrates' >> Frank Glaw.

<< Unfortunately, the habitat of the Nano-Chameleon is under heavy pressure from deforestation, but the area has recently been designated as a protected area, and hopefully that will enable this tiny new chameleon to survive, >> Oliver Hawlitschek.

Meet the nano-chameleon, a new contender for the title of world's smallest reptile. Staatliche Naturwissenschaftliche Sammlungen Bayerns. Feb 01, 2021. 

https://phys.org/news/2021-02-nano-chameleon-contender-title-world-smallest.html    

Glaw, F., Kohler, J., Hawlitschek, O. et al. Extreme miniaturization of a new amniote vertebrate and insights into the evolution of genital size in chameleons. Sci Rep 11, 2522. doi: 10.1038/ s41598-020-80955-1. Jan 28,  2021.

https://www.nature.com/articles/s41598-020-80955-1 

# chem: spontaneous reconfiguration of deformable nanoparticles (in response to environmental cues)

<< Deformable nanoparticles (NPs) offer unprecedented opportunities as dynamic building blocks that can spontaneously reconfigure during assembly in response to environmental cues. >>

<< deformable spherical NPs of radius 50 nm whose surface is tailored with octahedrally distributed charged patches and double-cap charged patches adapt their shape differently in response to changes in surface charge coverage and ionic strength. >>

AA << find shape transitions to rounded octahedra, faceted octahedra, faceted bowls, oblate spheroids, spherocylinders, dented beans, and dimpled rounded bowls. >>

AA << demonstrate that similar shape transitions can be achieved in deformable NPs of different sizes. >>️

Fanbo Sun, Nicholas E. Brunk, Vikram Jadhao. Shape control of deformable charge-patterned nanoparticles. Phys. Rev. E 107, 014502. Jan 10, 2023.

https://journals.aps.org/pre/abstract/10.1103/PhysRevE.107.014502

Img https://twitter.com/PhysRevE/status/1613183219377086468

Also

keyword 'self-assembly' in FonT

https://flashontrack.blogspot.com/search?q=self-assembly

keyword 'nano' in FonT

https://flashontrack.blogspot.com/search?q=nano

keyword 'nano' in Notes 

(quasi-stochastic poetry)

https://inkpi.blogspot.com/search?q=nano

Keywords: chem, nano, nanoparticles,  NPs, self-assembly, colloids, polymers, vesicle structures.

# gst: self‐assembly of porous, chiral nano-patterns from simple building blocks.

<< Using a simple rod-like building block with hydroxamic acids at both ends scientists (..) created self- assembling porous, chiral nano structures.  >>

<< Like our left and right hands, the shape of two mirrored cage structures cannot be superimposed. Since the 19th century, academics have characterized this type of object symmetry as 'chiral,' from the ancient Greek meaning 'hand.' These kinds of molecules are frequently found in natural compounds. Chirality influences interactions of polarized light and magnetic properties and plays a vital role in life.  For example, our olfactory receptors react very differently to the two mirror images of the limonene molecule: one smells like lemon, the other like pine. This so-called chiral recognition is a process that can determine whether a molecule acts as medicine or poison. >>

Complex, porous, chiral nano-patterns arise from a simple linear building blocks. Technical University Munich. Jan 16, 2020.

https://m.phys.org/news/2020-01-complex-porous-chiral-nano-patterns-simple.html

<< Regrettably (in this specific experimental context), the end groups proved to be elusive >>

Chao Jing,  Bodong Zhang, et al. Snapshots of Dynamic Adaptation: Two‐Dimensional Molecular Architectonics with Linear Bis‐Hydroxamic Acid Modules. Angewandte Chemie International Edition. Volume 58, Issue 52. doi: 10.1002/anie.201912247. Oct 31, 2019. 

https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201912247

Also

keyword 'chiral' in FonT

https://flashontrack.blogspot.com/search?q=chiral

# rmx-s-chem-nano: digital alchemy, a new frontier ...

<< Alchemy left the mainstream centuries ago, but one of its core concepts, transmuting the elements, is experiencing a revival in nanotechnology >>

http://www.nanowerk.com/nanotechnology-news/newsid=41725.php

<< (..) how to exploit the malleability of the valence of colloidal nanoparticle “elements” to directly and quantitatively link building-block attributes to bulk structure through a statistical thermodynamic framework we term “digital alchemy” >>

Greg van Anders, Daphne Klotsa et al., Digital Alchemy for Materials Design: Colloids and Beyond. ACS Nano, 2015, 9 (10), pp 9542–9553. DOI: 10.1021/acsnano.5b04181

http://pubs.acs.org/doi/10.1021/acsnano.5b04181

# e-bot: mimicking the structure of the "powdery alligator-flag" (Thalia dealbata)

<< Versatile, light-weight materials that are both strong and resilient are crucial for the development of flexible electronics, such as bendable tablets and wearable sensors. Aerogels are good candidates for such applications, but until now, it's been difficult to make them with both properties. Now, researchers report in ACS Nano that mimicking the structure of the "powdery alligator-flag" plant [Thalia dealbata] has enabled them to make a graphene-based aerogel that meets these needs. >>

Plant inspiration could lead to flexible electronics. June 21, 2017

https://m.phys.org/news/2017-06-flexible-electronics.html

Miao Yang, Nifang Zhao, et al. Biomimetic Architectured Graphene Aerogel with Exceptional Strength and Resilience. ACS Nano
doi: 10.1021/acsnano.7b01815 Publ. June 21, 2017

http://pubs.acs.org/doi/abs/10.1021/acsnano.7b01815

# s-chem: bimetallic nanodot arrays and electrochemical bias to ‘Chameleon’ plasmonic skin camouflage

<< [AA] have developed a way to produce colour-tuneable plasmonic metal nanostructures. They consist of a layer of nano-sized gold domes coated with a gel containing silver ions, all of which are sandwiched between two electrodes. Applying a positive voltage between the electrodes binds the silver ions to the gold domes, changing the characteristic plasmon reflectivity from red to green and finally blue; reversing the voltage takes the reflectivity back to the red end of the spectrum. >>

http://www.rsc.org/chemistryworld/2016/02/camouflage-plasmonic-skin-nanostructure-colour-change

Guoping Wang, Xuechen Chen, et al. Mechanical Chameleon through Dynamic Real-Time Plasmonic Tuning. ACS Nano, Article ASAP DOI: 10.1021/acsnano.5b07472

http://pubs.acs.org/doi/abs/10.1021/acsnano.5b07472

# gst: soft and stiff modes in colloidal particle networks

<< Floppy microscale spring networks are widely studied in theory and simulations, but no well-controlled experimental system currently exists. >> 

AA << show that square lattices consisting of colloid-supported lipid bilayers functionalized with DNA linkers act as microscale floppy spring networks. (AA) extract their normal modes by inverting the particle displacement correlation matrix, showing the emergence of a spectrum of soft modes with low effective stiffness in addition to stiff modes that derive from linker interactions. >>

<< Evaluation of the softest mode, a uniform shear mode, reveals that shear stiffness decreases with lattice size. >>

 AA << results reveal the importance of entropic steric effects. >>

️

Julio Melio, Silke E. Henkes, Daniela J. Kraft. Soft and Stiff Normal Modes in Floppy Colloidal Square Lattices. Phys. Rev. Lett. 132, 078202. Feb 14, 2024. 

https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.132.078202

Also: particle, nano, colloids, network, in https://www.inkgmr.net/kwrds.html

Keywords: gst, particle, nano, colloids, network, colloidal network

# s-chem-ethno: nanotech acupuncture needles

<< this experiment [..] combined nanotechnology with acupuncture needles >>

AA << developed porous acupuncture needles (PANs) with fine pores ranging in sizes from nanometers (one billionth of a meter) to micrometers (one millionth of a meter) on the surface of the needles using a nano-electrochemical method >>

<< PANs are expected to be as effective as conventional large and long needles by minimizing the sense of pain during acupuncture treatment while expanding the surface area of the needle 20 times greater than conventional acupuncture ones >>

<< Through electrophysiological experiments with rats [AA] proved that PANs excel in transferring signals from a spinal dorsal horn by the in vivo stimulation of Shenmen (HT7) points, and in particular, demonstrated that the efficacy of PANs is superior to conventional acupuncture needles in treating alcohol and cocaine addiction in animal experiments >>

Applying nanotechnology to make porous acupuncture needles. Oct 17, 2016.

http://www.nanowerk.com/nanotechnology-news/newsid=44827.php

Su-ll In, Young S. Gwak, et al. Hierarchical Micro/Nano-Porous Acupuncture Needles Offering Enhanced Therapeutic Properties. Nature. Scientific Reports 6, Article number: 34061 (2016)
doi:10.1038/srep34061

http://www.nature.com/articles/srep34061

# gst: local elastic properties of strongly disordered matter

<< The local elastic properties of strongly disordered material are investigated using the theory of correlated random matrices. A significant increase in stiffness is shown in the interfacial region, the thickness of which depends on the strength of disorder. It is shown that this effect plays a crucial role in nanocomposites, in which interfacial regions are formed around each nanoparticle. >>️

D. A. Conyuh, A. A. Semenov, Y. M. Beltukov. Effective elastic moduli of composites with a strongly disordered host material. Phys. Rev. E 108, 045004. Oct 20, 2023. 

https://journals.aps.org/pre/abstract/10.1103/PhysRevE.108.045004

Also: elastic, noise, particle, nano, in https://www.inkgmr.net/kwrds.html

Keywords: gst, elastic, noise, particle, nano

# gst: size, location and shape of interfacial nanobubbles can be tuned by nanostructures.

<< the nucleation mechanism of spontaneously generated NBs (nanobubbles) at solid-liquid interfaces of immersed nanostructured hydrophobic surfaces is studied. Depending on the size and density of the surface nanostructures, NBs with different size and density were reproducibly and deterministically obtained. >>️

moreover, << air entrapment experiments on a porous PS (coated polystyrene) surface covered with irregular nanopores show that also the shape of NBs can also be tuned by surface nanostructures, due to their pinning effect. It is thus feasible to tune NB size, position, and even morphology by varying surface nanostructures. >>️

Yuliang Wang, Xiaolai Li, et al. Entrapment of Interfacial Nanobubbles on Nano Structured Surfaces. arXiv:2208.08181v1 [physics.flu-dyn]. Aug 17, 2022.

https://arxiv.org/abs/2208.08181

Also

keyword "bubble" in FonT

https://flashontrack.blogspot.com/search?q=bubble

Keywords: gst, nano, bubble, tune, pinning effect️

# gst: approaching the dynamics of nanobubble formation and collapse

<< While sequential optical imaging (i.e., recording movies) has contributed significantly to our understanding of cavitation and other complex bubble behavior at the larger (..) scale, the necessary length and temporal resolutions make such a traditional approach infeasible for nanobubbles, >> Garth Egan. ️

<< To take the images at the nanoscale, (AA) shot a 532-nanometer laser pulse (about 12 nanosec) to excite gold nanoparticles inside a 1.2 micron layer of water. The resulting bubbles were observed with a series of nine electron pulses (10 ns) separated by as little as 40 ns peak-to-peak. The researchers found that isolated nanobubbles were observed to collapse in less than 50 ns, while larger (∼2–3 micron) bubbles were observed to grow and collapse in less than 200 ns. >>

<< Isolated bubbles were observed to behave consistently with models derived from data from much larger bubbles. The formation and collapse were observed to be temporally asymmetric, which has implications for how results from alternate methods of experimental analysis are interpreted. More complex interactions between adjacent bubbles also were observed, which led to bubbles living longer than expected and rebounding upon collapse. >>️️

Anne M. Stark. Multiframe imaging of micron and nanoscale bubble dynamics.  Lawrence Livermore National Laboratory. Feb 09, 2022. 

https://phys.org/news/2022-02-multiframe-imaging-micron-nanoscale-dynamics.html

Garth C. Egan, Edmond Y. Lau, Eric Schwegler.  Multiframe Imaging of Micron and Nanoscale Bubble Dynamics. Nano Lett. 2022, 22, 3, 1053–1058. doi: 10.1021/ acs.nanolett.1c04101. Jan 19, 2022.

https://pubs.acs.org/doi/10.1021/acs.nanolett.1c04101

Also

keyword "bubble" in FonT

https://flashontrack.blogspot.com/search?q=bubble

keyword "bolla" | "bolle" in Notes (quasistochastic-poetry): 

https://inkpi.blogspot.com/search?q=bolla

https://inkpi.blogspot.com/search?q=bolle

keywords: bubble, nano, nanobubble,  nanobubble dynamics, bubble formation, bubble collapse

# gst: exploring the lifespan of a liquid droplet

<< Current theories state that the droplet's diameter-squared decreases in proportion to time (classical law); however, this period only accounts for a small portion of the drop's evolution. As the diameter approaches the unobservable micro- and nano-scale, molecular dynamics have to be used as virtual experiments and these show a crossover to a new behaviour, with the diameter now reducing in proportion to time (nano-scale law). >>

<< It is fascinating that intuition based on everyday observations are a hindrance when attempting to understand nanoscale flows, so that, as in this research, one has to lean on theory to enlighten us. >>  James Sprittles.

The lifespan of an evaporating liquid drop. University of Warwick. Oct 10, 2019.     https://m.phys.org/news/2019-10-lifespan-evaporating-liquid.html

Rana A.S., Lockerby D.A., Sprittles J.E.  Lifetime of a Nanodroplet: Kinetic Effects and Regime Transitions. Phys. Rev. Lett. 123, 154501 Oct 9, 2019.     https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.123.154501   

# rmx-s-chem: a precise dance with 1 nm bubbles

<< ‘Bubble pen’ can precisely write patterns with nanoparticles as small as 1 nanometer >>

<< With this we might see the dawn of the nano machines >> (comment by  OranjeeGeneral, january 18, 2016)

http://www.kurzweilai.net/bubble-pen-can-precisely-write-patterns-with-nanoparticles-as-small-as-1-nanometer

L. Lin, X. Peng, et al.  Bubble-Pen Lithography. Nano Letters. Vol. 16: Issue. 1: Pages. 701-708. Publication Date (Web): December 17, 2015 DOI: 10.1021/acs.nanolett.5b04524

http://pubs.acs.org/doi/abs/10.1021/acs.nanolett.5b04524

# gst: intertwining order, disorder, and hierarchy

<< Nature hosts a wealth of materials showcasing intricate structures intertwining order, disorder, and hierarchy, delivering resilient multifunctionality surpassing perfect crystals or simplistic disordered materials. The engineering of such materials through nanoparticle assembly represents a burgeoning field, poised with potential to yield sustainable material systems rivaling or exceeding biological functionalities. >>

AA << review delineates the fundamental concept of complexity in the context of nanoscale materials. >>

Xiaoming Mao, Nicholas Kotov. Complexity, Disorder, and Functionality of Nanoscale Materials. arXiv: 2401.09567v1 [cond-mat.soft]. Jan 17, 2024. 

https://arxiv.org/abs/2401.09567

Also: nano, particle, order, disorder, in  https://www.inkgmr.net/kwrds.html

Keywords: nano, particle, order, disorder 

# ai-bot: a campaign to stop killer bots (i.e. near-future ubiquitous lethal autonomous weapons - nfulaw)

<< In response to growing concerns about autonomous weapons, the Campaign to Stop Killer Robots, a coalition of AI researchers and advocacy organizations, has released a fictional video that depicts a disturbing future in which lethal autonomous weapons have become cheap and ubiquitous worldwide >>

Disturbing video depicts near-future ubiquitous lethal autonomous weapons. The technology described in the film already exists, says UC Berkeley AI researcher Stuart Russell. Nov 18, 2017

http://www.kurzweilai.net/disturbing-video-depicts-near-future-ubiquitous-lethal-autonomous-weapons

FonT

in effetti si puo' immaginare - senza sconfinare troppo nella fantascienza - una entita' "nfulaw"  nella forma funzionale del bot-mosquito, di pochi millimetri, armata di device a pungiglione e adatte nano-vescicola e nano-pompa - in grado di iniettare qualche sorta di micidiale molecola -  che traccia e individua il suo bersaglio tramite il riconoscimento facciale oppure attraverso il segnale dello smartphone ...

# gst: approaching chaotic dynamics to trace the complexity of rough nanostructured surfaces

AA << use the basic ingredients of chaotic dynamics (stretching and folding of phase space points) for the characterization of the complexity of microscopy images of rough surfaces. The key idea is to use an image as the initial condition of a chaotic discrete dynamical system, such as the Arnold cat map, and track its transformations during the first iterations of the map. Since the basic effects of the Arnold map are the stretching and folding of image texture, the application of the map leads to an enhancement of the high frequency content of images along with an increase of discontinuities in pixel intensities. (AA) exploit these effects to quantify the complexity of S type (lying between homogeneity and randomness) of the image texture since the first (enhancement of high frequencies) can be used to quantify the distance of texture from randomness and noise and the second (the proliferation of discontinuities) the distance from order and homogeneity. The method is validated in synthetic images which are generated from computer generated surfaces with controlled correlation length and fractal dimension and it is applied in real images of nanostructured surfaces obtained from a scanning electron microscope with very interesting results. >>️

A. Kondi, V. Constantoudis, P. Sarkiris, K. Ellinas, and E. Gogolides. Using chaotic dynamics to characterize the complexity of rough surfaces. Phys. Rev. E 107, 014206. Jan 11, 2023. 

https://journals.aps.org/pre/abstract/10.1103/PhysRevE.107.014206

https://twitter.com/PhysRevE/status/1613569770338533376

Also

Able to track changes in noise. 

(quasi-stochastic poetry) 

Notes. Sep 13, 2007. 

https://inkpi.blogspot.com/2007/09/2147-able-to-track-changes-in-noise.html

Also

keyword 'chaos' | 'chaotic' in Font

https://flashontrack.blogspot.com/search?q=chaos

https://flashontrack.blogspot.com/search?q=chaotic

keyword 'caos' | 'caotico' in Notes (quasi-stochastic poetry)

https://inkpi.blogspot.com/search?q=caos

https://inkpi.blogspot.com/search?q=caotico

Keywords: gst, chaos, chaotic, nano, roughness, wetting, surfaces, etching scanning 

# gst: apropos of unexpected Hopfion tangles

<< a certain geometrical structure of knots, which scientists call a Hopfion, manifests itself in unexpected corners of the universe, ranging from particle physics, to biology, to cosmology. >>

<< In a recent theoretical study, (..) (AA) discovered the presence of the Hopfion structure in nano-sized particles of ferroelectrics. >>

<< The Hopfion is a very abstract mathematical concept, (..) but the structure shows up in hydrodynamics, electrodynamics and even in the packing of DNA and RNA molecules in biological systems and viruses. >> Valerii Vinokur

<< When we visualized the polarization, we saw the Hopfion structure emerge, (..) We thought, wow, there is a whole world inside of these nanoparticles. >> Igor Luk'yanchuck.

Savannah Mitchem. Novel insight reveals topological tangle in unexpected corner of the universe. Argonne National Laboratory. May 26, 2020.

https://phys.org/news/2020-05-insight-reveals-topological-tangle-unexpected.html

Luk’yanchuk I., Tikhonov Y., et al. Hopfions emerge in ferroelectrics. 

 Nat Commun 11, 2433. doi: 10.1038/ s41467-020-16258-w. May 15, 2020.

https://www.nature.com/articles/s41467-020-16258-w

# s-tech: DNA as a nano transistor

<< As electronics get smaller they are becoming more difficult and expensive to manufacture, but DNA-based devices could be designed from the bottom-up using directed self-assembly techniques such as ‘DNA origami’ >>

http://www.kurzweilai.net/will-this-dna-molecular-switch-replace-conventional-transistors

Juan Manuel Artés, Yuanhui Li,  et al. Conformational gating of DNA conductance. Nature Communications, 2015; 6: 8870 DOI: 10.1038/ncomms9870

http://www.nature.com/ncomms/2015/151209/ncomms9870/full/ncomms9870.html